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The carbamate derived from aminoimidazole is an intermediate in the biosynthesis of inosine, carbamoyl phosphate is generated from carboxyphosphate rather than CO2. Perhaps the most important carbamate is the one involved in the capture of CO2 by plants since this process is necessary for their growth, the enzyme ribulose 1, 5-bisphosphate carboxylaseoxygenase fixes a molecule of carbon dioxide as phosphoglycerate in the Calvin cycle. At the active site of the enzyme, a Mg2 ion is bound to glutamate and aspartate residues as well as a lysine carbamate. The carbamate is formed when an uncharged lysine side chain near the ion reacts with a carbon dioxide molecule from the air, which renders it charged.

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