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Perhaps the most important carbamate is the one involved in the capture of CO2 by plants since this process is necessary for their growth, the enzyme ribulose 1, 5-bisphosphate carboxylaseoxygenase fixes a molecule of carbon dioxide as phosphoglycerate in the Calvin cycle. At the active site of the enzyme, a Mg2 ion is bound to glutamate and aspartate residues as well as a lysine carbamate. The carbamate is formed when an uncharged lysine side chain near the ion reacts with a carbon dioxide molecule from the air, which renders it charged. The so-called carbamate insecticides feature the carbamate ester functional group, included in this group are aldicarb, carbofuran, carbaryl, ethienocarb, fenobucarb, oxamyl, and methomyl.

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